Highlanders and Dynamos both had a Monday afternoon to forget after they were both beaten by a solitary goal in their respective matches.
Bosso lost 1-0 to Triangle on Monday afternoon and remain on two points after Matchday 4.
The Sugar Boys scored through Nyasha Chintuli to secure their second ever league win over the Bulawayo giants.
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Herentals beat Dynamos 1-0 at Rufaro Stadium to prolong the former Glamour Boys’ misery.
Juan Mutudza scored a late goal to down DeMbare and leave coach Lloyd Chigowe sweating over his job.
Elsewhere, Stephen Sibanda scored the solitary goal for Manica Diamonds against Mushowani Stars in a match played at Gibbo Stadium.
Dynamos 0-1 Herentals
Highlanders 0-1 Triangle United
Manica Diamonds 1-0 Mushowani Stars